Terpolymerization of Styrene, Norbornene, and Carbon Monoxide with a Palladium Catalyst

Oxidation of Carbon Monoxide by Oxygen on Palladium and Ruthenium Catalyst

Recently, the authors described the catalytic elimination of nitrogen oxide from crm hydrogen [1], in the course of which a secondary contamination of gas with cark dioxide occurred in a plant in Slovakia. This fact stimulated the authors to study th undesirable reaction, i.e. oxidation of carbon monoxide by oxygen. The oxidation of carbon monoxide with respect to industrial usage has been stud...

a comparison of teachers and supervisors, with respect to teacher efficacy and reflection

supervisors play an undeniable role in training teachers, before starting their professional experience by preparing them, at the initial years of their teaching by checking their work within the proper framework, and later on during their teaching by assessing their progress. but surprisingly, exploring their attributes, professional demands, and qualifications has remained a neglected theme i...

[C]Carbon Monoxide in Rhodium-/Palladium-Mediated Carbonylation Reactions

Palladium(II)-catalyzed copolymerization of styrenes with carbon monoxide: mechanism of chain propagation and chain transfer.

A mechanistic interpretation of the [(1,10-phenanthroline)Pd(CH(3))(CH(3)CN)](+)[BArF](-) (1a) and [(2,2'-bipyridine)Pd(CH(3))(CH(3)CN)](+)[BArF](-) (1b) (BArF = 3,5-(CF(3))(2)-C(6)H(3)) catalyzed perfectly alternating copolymerization of styrenes with CO is reported. The copolymerization in CH(2)Cl(2) or chlorobenzene has been found to be first order in styrene and inverse first order in CO co...

Palladium-catalyzed ring-opening thiocarbonylation of vinylcyclopropanes with thiols and carbon monoxide.

Palladium-catalyzed ring-opening thiocarbonylation of vinylcyclopropanes (VCPs) with thiols and carbon monoxide affords the corresponding unsaturated thioesters in moderate to excellent yields. This reaction provides a general method for the ring-opening thiocarbonylation of VCPs. It further demonstrates the utility of transition metal catalysts for the synthesis of organosulfur compounds.